Hi chugalone 100 Welcome to the site.
You can fibreglass with different types of resin and cloth. if you are making and casting a fibreglass hull use fibreglass matting but to cover a hull lightweight fibreglass cloth is best. This is the type shown in the suggested video.
Resin can be epoxy or polyester based but the latter is generally cheaper and in my opinion is easier to use and doesn't require thinning with alcohol. it is sold as layup resin and is supplied with hardener. Do follow the instructions re quantity of each part and mix thoroughly.
If you are using epoxy iso Propyl Alcohol is the type to use and is clear.
The video shows using a brush to apply the resin and whilst this is OK it will give a very thick and heavy coating. I use the brush to apply and then a credit card sized piece of plasticard to spread the resin over and into the surface of the cloth resulting in an almost opaque finish with the weave showing through. You do need to have a good surface to work with as any imperfections will show when the resin hardens. Once dry give a light sanding all over to remove any imperfections and fill any holes with car body filler and sand smooth. I then apply a very thin top coat of the resin using a brush. When dry use wet and dry to sand and if necessary apply further thin coats until you have the finish you require. I have a local supplier and if you visit the site
http://www.resin-supplies.co.uk/product.htm all the resins/cloths etc are listed. Using Google should bring up a local supplier.
you do need to follow the safety instructions to protect yourself and wear appropriate protection for your hands, eyes and breathing, it is also best to apply in a well ventilated area and not on a cold day.
The end result will be well worth the effort to keep your tug waterproof. You could also paint the resin over thye inside of the hull to protect the wood from any water that doeos find its way inside.
Dave